Gambieroxide, a novel epoxy polyether compound from the dinoflagellate Gambierdiscus toxicus GTP2 strain
β Scribed by Watanabe, Ryuichi; Uchida, Hajime; Suzuki, Toshiyuki; Matsushima, Ryoji; Nagae, Mika; Toyohara, Yoshikazu; Satake, Masayuki; Oshima, Yasukatsu; Inoue, Akio; Yasumoto, Takeshi
- Book ID
- 122146727
- Publisher
- Elsevier Science
- Year
- 2013
- Tongue
- French
- Weight
- 598 KB
- Volume
- 69
- Category
- Article
- ISSN
- 0040-4020
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The axial C6-OH group in gambierol isolated from the dinoflagellate, Gambierdiscus toxicus, was inverted to equatorial disposition and esterified with (S)-and (R)-MTPA. NMR analysis of these esters established S configuration at C6, thus allowing determination of the absolute configuration of the wh
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