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Furylcyclohexenones. Part 3. Synthesis and Properties of 6-Acetyl-3(5)-furylcyclohex-2-enones. Molecular and Crystal Structure of 6-Acetyl-3-(2-furyl)-5-phenylcyclohex-2-enone.

✍ Scribed by E. B. Usova; L. I. Lysenko; V. E. Zavodnik; E. K. Yablonskaya; G. D. Krapivin


Publisher
John Wiley and Sons
Year
2004
Weight
87 KB
Volume
35
Category
Article
ISSN
0931-7597

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Enantioconvergent synthesis of (βˆ’)-(S)-
✍ V.G. Zaitsev; A.L. Mikhal'chuk πŸ“‚ Article πŸ“… 2001 πŸ› John Wiley and Sons 🌐 English βš– 129 KB

## Abstract The synthesis of enantiomerically pure (βˆ’)‐(__S__)‐ and (+)‐(__R__)‐2‐acyl‐3,6‐dihydroxycyclohex‐2‐enone starting from diastereomerically pure N‐tosyl‐(__S__)‐proline esters 3‐methoxy‐6‐hydroxycyclohex‐2‐enone **1** is presented. An enantioconvergent synthesis of either (βˆ’)‐(__S__)‐ and