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Further Study of the Reaction of Fe 2+ with CN - : Synthesis and Characterization of cis and trans [Fe II,III (CN) 4 L 2 ] n - Complexes

✍ Scribed by Chiarella, Gina M.; Melgarejo, Doris Y.; Koch, Stephen A.

Book ID
120267257
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
61 KB
Volume
128
Category
Article
ISSN
0002-7863

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## Abstract The reaction Fe(CN)~4~(bpy)^2−^ + S~2~O~8~^2−^ has been studied in aqueous micellar solutions of __N__‐tetradecyl‐__N,N__‐dimethyl‐3‐ammonio‐1‐propanesulfonate, SB3‐14. The influence of changes in the surfactant concentration as well as in the peroxodisulfate ions concentration on __k__

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## Abstract Salt effects on the oxidation of the iron(II) complexes Fe(CN)~4~(bpy)^2−^, __cis__‐(CN)~2~(bpy)~2~ and Fe(bpy)~3~^2+^ by S~2~O~8~^2−^ as well as on the reaction Fe^2+^ + Co(NH~3~)~5~Cl^2+^ have been studied in concentrated electrolyte solutions at 298.2 K. We have gone from anion–anion