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Further Studies on the Energy Difference between the Chair and Twist Forms of Cyclohexane

✍ Scribed by Margrave, John L.; Frisch, Margaret A.; Bautista, Renato G.; Clarke, Robert L.; Johnson, William S.


Book ID
127266267
Publisher
American Chemical Society
Year
1963
Tongue
English
Weight
418 KB
Volume
85
Category
Article
ISSN
0002-7863

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NMR experiments on acetals—XXV: Conforma
✍ M. Anteunis; G. Swaelens 📂 Article 📅 1970 🏛 John Wiley and Sons 🌐 English ⚖ 422 KB

## Abstract __Trans__‐4‐__t__‐Bu‐6‐R‐1,3‐dioxanes (R = Me, Pr^i^ and __cyclo__hexyl) show temperature‐dependent values for ^2^__J__(H—2) and ^3^__J__(H—4(6), H—5) in their PMR spectra. This is the result of the presence of twist‐boat conformations. With the aid of typical limit‐values of ^2^__J__(H