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Further studies on polycyclic arene sulfides. Preparation and mutagenic activity of 9, 10, 10a, 11a-tetrahydrotriphenyleno[1,2-b]-thiirene, 1a,2,3,10b-tetrahydro-5H-thiereno[3,4]benzo[1,2-b]fluorene and 1a,2,3,11b-tetrahydroacenaphtho[1′,2′:6,7]naphth[1,2-b]thiirene

✍ Scribed by Jochanan Blum; Vladimir Kogan; Hansruedi Glatt

Publisher
Journal of Heterocyclic Chemistry
Year
2000
Tongue
English
Weight
249 KB
Volume
37
Category
Article
ISSN
0022-152X

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✦ Synopsis

Abstract

The title compounds 6, 8 and 10, which are dihydroarene sulfides of the environmental pollutants triphenylene, benzo[b]fluorene and benzo[k]fluoranthene, have been synthesized from the corresponding epoxides and N,N‐dimethylthioformamide. The mutagenicity of the episulfides has been investigated using Salmonella typhimurium strains TA98 and TA100. While compounds 6 and 10 were mutagenic, the tetrahydrobenzo[b]fluorene episulfide 8 was inactive.

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