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Further Investigations of the ClO Rotational Spectrum

✍ Scribed by Brian J. Drouin; Charles E. Miller; Edward A. Cohen; Georg Wagner; Manfred Birk

Publisher: Elsevier Science
Year: 2001
Tongue: English
Weight: 103 KB
Volume: 207
Category: Article
ISSN: 0022-2852
DOI: 10.1006/jmsp.2001.8332

No coin nor oath required. For personal study only.

✦ Synopsis

Pure rotational transitions of the chlorine monoxide radical have been observed

states and transitions of the 35 Cl 18 O isotopomer have been observed in natural abundance. Additionally, rotational transitions for levels up to J = 115/2 have been measured in the far infrared. These data have been merged with the existing microwave, submillimeter, and high-resolution infrared transition frequencies and fit simultaneously with a set of isotopically independent parameters. Isotopic substitution of both the Cl and O atoms has enabled the first determination of the electron spin-rotation constant γ = -296.0(43) MHz as well as the Born-Oppenheimer corrections to the rotational constants.

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