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Further experiments on a new, fast method for determining molecular weights of diffusing species in a liquid phase

โœ Scribed by Conrad N. Trumbore; Mark Grehlinger; Michele Stowe; Frances M. Keleher


Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
891 KB
Volume
322
Category
Article
ISSN
1873-3778

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โœฆ Synopsis


Further experiments have been conducted on a previously reported method for determining empirically the molecular weight of a series of proteins on the basis of the shape of the concentration profile of the protein sample exiting from a capillary after injection of that sample in plug form into a mobile phase which exhibits laminar flow in the capillary. The method depends upon the influence of the relative amounts of convection and radial molecular diffusion in determining the shape of the concentration vs. time profile of the capillary effluent detected by a concentration detector at the capillary outlet. Two times on the concentration profile are chosen to reflect


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