Further examples of skeletal rearrangements of the Wagner-Meerwein type in chemical ionization mass spectrometry: The case of [C6H9]+ ions

Hydrogen migrations in mass spectrometry

Hydrogen migrations in mass spectrometry. IV—formation of [C6H7]+ in the chemical ionization mass spectra of alkylbenzenes

✍ Hei-Wun Leung; Alex. G. Harrison 📂 Article 📅 1977 🏛 John Wiley and Sons 🌐 English ⚖ 450 KB

Using specific deuterium labelling the mechanisms of the olefin elimination reactions leading to formation of [C,H,]+ in the H, and CH, chemical ionization mass spectra of ethylbenzene and n-propylhenzene (and to [C,H,C,HJ+ in the CH, chemical ionization mass spectra) have been investigated. The res