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Further development of a versatile microscale automated workstation for parallel adaptive experimentation

✍ Scribed by David G. Cork; Tohru Sugawara; Jonathan S. Lindsey; L. Andrew Corkan; Hai Du


Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
228 KB
Volume
11
Category
Article
ISSN
0895-7533

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✦ Synopsis


We have further developed our microscale automated chemistry workstation for investigating the optimization of reaction conditions. The workstation includes a Cartesian robot for solvent delivery and reagent/sample handling, a 60-vessel reaction block, a UV-Vis absorption spectrometer, and vial racks for compound storage. This article describes the following hardware additions that increase the scope and versatility of the workstation: (a) an analytical high performance liquid chromatography (HPLC) instrument and accompanying hardware interface (slide rail, autosampler); (b) three reactor blocks of 20 vessels each, with independent temperature control of each reactor block between ca. 0 and 80ЊC; (c) a shaker rack for mixing, dilution, or extraction of samples; (d) a rotary valve on the dispense line for complete isolation of 4 independent solvent lines; (e) sample workup features using disposable cartridges or filters; (f) provisions for dispensing inert gas, for example, for flushing through reactors or for storing solvents and performing trans-