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Further ab initio studies on the reactivity of nitrosoketene

✍ Scribed by Sihyun Ham; David M. Birney

Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
220 KB
Volume
38
Category
Article
ISSN
0040-4039

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✦ Synopsis

The cycloadditions of nitrosoketene with formaldehyde, acetone and 2-propenal were calculated using ab initio molecular orbital theory (MP2/6-31G*). The reactions proceed by the [3+2] pathway via a concerted, planar and pseudopericyclic transition state with a significantly lower barrier

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