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Furopyridines. XV. Synthesis and properties of ethyl 2-(3-furo[2,3-b]-, -[3,2-b]-, -[2,3-c]- and -[3,2-c]pyridyl)acetate

✍ Scribed by Shunsaku Shiotani; Masahiko Tsuno; Noriyasu Tanaka; Miho Tsuiki; Makoto Itoh

Book ID: 112131133
Publisher: Journal of Heterocyclic Chemistry
Year: 1995
Tongue: English
Weight: 901 KB
Volume: 32
Category: Article
ISSN: 0022-152X
DOI: 10.1002/jhet.5570320122

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## Abstract Bromination of α‐cyanopyridine derivatives of furopyridines 1a‐d gave the 2,3‐dibromo‐2,3‐dihydro compounds 2a‐d in excellent yields. Treatment of 2a‐d with sodium hydroxide in methanol yielded compounds formed through the dehydrobromination and solvolysis of the nitrile. __N__‐Oxidatio