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Furans as intermediates for the synthesis of oxygenated natural products. Asymmetric synthesis of Prelog-Djerassi lactone.

✍ Scribed by Stephen F. Martin; Denise E. Guinn


Book ID
104242581
Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
185 KB
Volume
25
Category
Article
ISSN
0040-4039

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1,2 Asymmetric induction in the cyclic h
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## Cyclic hydroboration of an appropriately substituted 1.5~diene yields a 1,5 dial as the major product which can be converted to the racemic Prelog-Djerassi lactone. The widespread occurrence of the three carbon unit 1 in natural products of current synthetic interest has prompted us to investig