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Furan synthesis by 1,4 addition of carboethoxycarbene to α-methoxymethylene ketones

✍ Scribed by David L. Storm; Thomas A. Spencer


Book ID
104223883
Publisher
Elsevier Science
Year
1967
Tongue
French
Weight
111 KB
Volume
8
Category
Article
ISSN
0040-4039

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1,4-Addition of triorganozincates and si
✍ Tückmantel, Werner ;Oshima, Koichiro ;Nozaki, Hitosi 📂 Article 📅 1986 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 683 KB

Lithium and magnesium triorganozincates, prepared by combination of ZnC12(TMEDA) with 3 molar equivalents of RLi or RMgX, or from dialkylzinc and 1 molar equivalent of RLi or RMgX, react with 2-cyclohexen-1-one (1) under mild conditions to produce moderate to good yields of the 1 &addition products