GCEMC molecular simulations of methane adsorption in model slit-shaped carbon pores show that variations in the density of carbon atoms in the pore wall have a significant influence on adsorbed methane density, although variations in inter-layer spacing and the number of layer planes in the pore wal
Fundamentals of methane adsorption in microporous carbons
✍ Scribed by J. Alcañiz-Monge; D. Lozano-Castelló; D. Cazorla-Amorós; A. Linares-Solano
- Publisher
- Elsevier Science
- Year
- 2009
- Tongue
- English
- Weight
- 724 KB
- Volume
- 124
- Category
- Article
- ISSN
- 1387-1811
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At the basis of the theory of vapor adsorption in the micropores of carbon adsorbents of the most probable slit-like, limited-size type lie the dispersion interactions between the adsorbate and adsorbent atoms as well as between the atoms of the adsorbed substance themselves. As a consequence of com
Adsorption energies for different surface and pore configurations were calculated by summing the Lennard-Jones potential for the interaction of an adsorbate molecule with the carbon surface. The calculations provide information on the adsorption potential as a function of pore configuration and spac