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Fundamentals and Transition-State Models. Aldol Additions of Group 1 and 2 Enolates

✍ Scribed by Manfred Braun

Publisher
John Wiley and Sons
Year
2006
Weight
8 KB
Volume
37
Category
Article
ISSN
0931-7597

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The Chemistry of Chlorosilyl Enolates. Part 3. Variation of the Silyl Group and the Effect on Rate and Enantiomeric Excess of Acetate Aldol Additions. -Silyl ketene acetals (I) and (IV) react with aldehydes (II) and (V) in the presence of catalytic amounts of chiral phosphoramides to yield the ester