✦ LIBER ✦

Fundamental study of the reaction of epoxy-bearing polymers with 4-hydroxybenzoic acid application to the synthesis of chelating polymers—1: Kinetic study of the reaction carried out on models

✍ Scribed by E. Colette Crepeau; Maréchal

Publisher: Elsevier Science
Year: 1983
Tongue: English
Weight: 383 KB
Volume: 19
Category: Article
ISSN: 0014-3057
DOI: 10.1016/0014-3057(83)90003-4

No coin nor oath required. For personal study only.

✦ Synopsis

In order to prepare chelating polymers and metalliferous dyes, chemical modification of poly(butylacrylate-co-glycidylmethacrylate) is carried out. The present article refers to the study of this modification using models. Two compounds are chosen, viz. glycidyl isobutyrate which is a model for one monomer unit and digiycidyl-2,4 dimethylglutarate which is a model for two consecutive monomer units. The syntheses of these models are described; the kinetics of their reaction with 4-hydroxybenzoic acid are studied. Orders in catalyst (dimethyldodecylamine) and in reactants are respectively I and 1.5 for both models. Rate constants are determined in various solvents. The results fit Madec's pattern.

📜 SIMILAR VOLUMES

Fundamental study of the reaction of epo

Fundamental study of the reaction of epoxy-bearing polymers with 4-hydroxybenzoic acid application to the synthesis of chelating polymers—II: Modification of a poly(butyl acrylate-co-glycidyl methacrylate) by 4-hydroxybenzoic acid—synthesis of a polymeric dye

✍ Colette Crepeau; E. Maréchal 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 427 KB

A~trae~In first part [l] [Eur. Polym. J. 19, 1099 (1983)] the reaction of 4-hydroxybenzoic acid with epoxy groups was studied on models. The present article is devoted to the same reaction, when carried out on poly(butylacrylate-co-glycidylacrylate). It appears that the behaviour of this system is f