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Functionalized magnesium organometallics as versatile intermediates for the synthesis of polyfunctional heterocycles

โœ Scribed by Ila, Hiriyakkanavar ;Baron, Oliver ;Wagner, Andreas J. ;Knochel, Paul

Book ID
120204260
Publisher
Royal Society of Chemistry
Year
2006
Tongue
English
Weight
433 KB
Volume
6
Category
Article
ISSN
1359-7345

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Functionalized Magnesium Organometallics
Functionalized Magnesium Organometallics as Versatile Intermediates for the Synthesis of Polyfunctional Heterocycles
โœ Hiriyakkanavar Ila; Oliver Baron; Andreas J. Wagner; Paul Knochel ๐Ÿ“‚ Article ๐Ÿ“… 2006 ๐Ÿ› John Wiley and Sons โš– 8 KB ๐Ÿ‘ 2 views

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Acylnitrilium ions. Versatile new interm
Acylnitrilium ions. Versatile new intermediates for the Synthesis of highly functionalized heterocycles.
โœ Gregory Luedtke; Mark Westling; Tom Livinghouse ๐Ÿ“‚ Article ๐Ÿ“… 1992 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 1003 KB

Acylnitrilium ions, generated by the exposure of tu-ketoimidoyl chlorides to AgBF, readily engage suitably disposed sites of molecular unsaturation in cyclization reactions leading to heterocyclic ring systems. This novel method for annulation is applicable to the construction of 5, 6, and 7 membere