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Functionalized dihydropyridines do reduce alkoxycarbene complexes of chromium and give access to polycyclic butenolides

✍ Scribed by Henri Rudler; Andrée Parlier; Victor Certal; Jean-Cédric Frison


Book ID
104429962
Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
110 KB
Volume
4
Category
Article
ISSN
1387-1609

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Reaction of nucleophiles with alkoxycarb
✍ Henri Rudler; Andrée Parlier; Victor Certal; Nadège Humbert; Jacqueline Vaisserm 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 58 KB

A series of new substituted butenolides has been obtained either by reacting alkynylalkoxycarbene complexes 3 with simple nucleophiles such as metal hydrides, metal alkoxides and metal alkyls, or by reacting simple alkoxycarbene complexes 6 with more elaborate nucleophiles such as metal alkynolates