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Functionalized Chiral Ionic Liquid Catalyzed Asymmetric SN1 α-Alkylation of Ketones and Aldehydes

✍ Scribed by Long Zhang; Lingyun Cui; Xin Li; Jiuyuan Li; Sanzhong Luo; Jin-Pei Cheng


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
830 KB
Volume
2010
Category
Article
ISSN
1434-193X

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Palladium-Catalyzed Asymmetric Allylic A
✍ Barry M. Trost; Gretchen M. Schroeder; Jesper Kristensen 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 115 KB 👁 1 views

The generation of quatenary chiral centers through catalytic asymmetric alkylation of ketone enolates has been the subject of investigation in recent years. [1] The palladiumcatalyzed asymmetric allylic alkylation (AAA) of prochiral nucleophiles represents one such strategy for the creation of quate