Functionalized Carbocyclic Rings via Intramolecular Diels-Alder Reactions of in situ Generated, γ Substituted, Heteroatom-Stabilized Allyl Cations in Acidic Polar Media. -Slow addition of substrates such as (I) and (III) to a solution of lithium perchlorate and catalytic TFA generates oxygen stabil
✦ LIBER ✦
Functionalized carbocyclic rings via intramolecular Diels-Alder reactions of in situ-generated, γ substituted, heteroatom-stabilized allyl cations in acidic polar media
✍ Scribed by Paul A. Grieco; Michael D. Kaufman
- Book ID
- 104260589
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- French
- Weight
- 221 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
The synthesis of highly structured carbocyclic ring systems possessing quaternary carbon atoms has been realized v/a intramolecular Diels-Alder reactions of in sire-generated, 7 substituted, heteroatom-stabilized allyl cations in acidic polar media.
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