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Functionalized 2,2‘-Bipyridines and 2,2‘:6‘,2‘ ‘-Terpyridines via Stille-Type Cross-Coupling Procedures

✍ Scribed by Heller, Marcel; Schubert, Ulrich S.

Book ID
120610484
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
89 KB
Volume
67
Category
Article
ISSN
0022-3263

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5,5″-Disubstituted 2,2′:6′,2″-Terpyridin
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✍ Uwe Lehmann; Oliver Henze; A. Dieter Schlüter 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 141 KB 👁 1 views

The 0.3 ± 5 g scale syntheses of the 2,2':6',2''-terpyridines 3, 6, 9, and 10 are described. The pyridine units are connected to one another by Pd-catalyzed crosscoupling reactions. This method allows the easy introduction of halogen, stannyl, and boronic ester functionalities at positions C-5 and C