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Functionalization of Porphyrins: Mechanistic Insights, Conformational Studies, and Structural Characterizations

✍ Scribed by Zakaria Halime; Sébastien Balieu; Mohammed Lachkar; Thierry Roisnel; Philippe Richard; Bernard Boitrel


Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
244 KB
Volume
2006
Category
Article
ISSN
1434-193X

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The new diiron complex [Fe 2 (tbpo){O 2 As(CH 3 ) 2 }(CH 3 O)-hydroxo-bridged complex [Fe 2 (tbpo)(OH)(NO 3 ) 2 ](NO 3 ) 2 • CH 3 OH • 2 H 2 O (2) was employed. The reactions of 1 and 2 with H 2 O 2 were studied as a function of [H 2 O 2 ], pH, temperature, and pressure, and the kinetic results inc