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Functionalization of polysiloxanes by esterification of pendant glycidic groups: Acetylation as a model reaction

✍ Scribed by X. Coqueret; A. Lablache-Combier; C. Loucheux

Book ID: 103074212
Publisher: Elsevier Science
Year: 1988
Tongue: English
Weight: 365 KB
Volume: 24
Category: Article
ISSN: 0014-3057
DOI: 10.1016/0014-3057(88)90003-1

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✦ Synopsis

The esterification of polysiloxane-bound epoxy groups provides a versatile route to functionalized silicone copolymers. The model reaction of acetic acid with pendant glycidic groups in the presence of a tertiary amine as a catalyst was investigated. Chromatographic and spectroscopic studies of the resulting polysiloxanes showed that no detectable unwanted side-reaction takes place when the reaction is carried out under mild conditions; long-chain polysiloxanes having high functionalization rate were obtained as gummy products almost insoluble in toluence because of stronger inter-molecular associations by hydrogen-bonding. Convenient flow properties as well as good solubility in common organic solvents could, however, be easily achieved upon acetylation of hydroxylic groups.

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