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Functionalization of polymeric organolithium compounds. Amination of poly(styryl)lithium

✍ Scribed by Quirk, Roderic P.; Cheng, Pao Luo

Book ID
127033023
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
479 KB
Volume
19
Category
Article
ISSN
0024-9297

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πŸ“œ SIMILAR VOLUMES

Quantitative amine functionalization of
Quantitative amine functionalization of polymeric organolithium compounds with 3-dimethylaminopropyl chloride in the presence of lithium chloride
✍ Roderic P. Quirk; Youngjoon Lee πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 English βš– 141 KB πŸ‘ 2 views

The addition of lithium chloride promoted the coupling reaction of hydrocarbon solutions of poly(styryl)lithium (PSLi) and poly(isoprenyl)lithium (PILi) with 3-dimethylaminopropyl chloride to form the corresponding -dimethylamino-functionalized polymers. Quantitative amine functionalization was achi

Functionalization and Linking Chemistry
Functionalization and Linking Chemistry of Poly(styryl)lithium with 1,3-Butadiene Diepoxide
✍ Roderic P. Quirk; Asfiya Contractor; Michael J. Polce; Chrys Wesdemiotis πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 English βš– 179 KB

## Abstract **Summary:** The reaction of excess poly(styryl)lithium ($\overline M \_{\rm n}$ = 1 400 g · mol^βˆ’1^) with 1,3‐butene diepoxide proceeds efficiently to produce a coupled product with two in‐chain hydroxyl groups. The pure coupled, functionalization product was isolated in quantitative y