Functionalization and Cyclization Reactions of Various Acetanilides with 4-Benzoyl-5-phenyl-2,3-furandione. Experimental and Theoretical Investigations. -The title furandione (I) reacts with acetanilides (II) to furnish new open chain dibenzoylacetic acid derivatives (III) or (IV) or the new oxazol
Functionalization and cyclization reactions of various acetanilides with 4-benzoyl-5-phenyl-2,3-furandione. Experimental and theroetical investigations
✍ Scribed by Ismail Yildirim; I. Özer Ilhan
- Publisher
- Journal of Heterocyclic Chemistry
- Year
- 1997
- Tongue
- English
- Weight
- 319 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0022-152X
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✦ Synopsis
Abstract
4‐Benzoyl‐5‐phenyl‐2,3‐furandione (1) reacts with acetanilides 3a‐c under different conditions and gives the new open chained dibenzoylacetic acid derivatives 5a‐c, 6 and a new heterocyclic compound such as oxazole derivative 7. The electronic structures of the reactants, transitional states and final products of the reactions are investigated on the basis of AM1 method.
📜 SIMILAR VOLUMES
## Abstract 1‐Amino‐5‐benzoyl‐4‐phenyl‐1__H__‐pyrimidine‐2‐one **1** reacts with several carboxylic anhydrides **2a‐d** under different conditions and gives new amide and imide derivatives. The structure of these compounds, **3a‐d**, are determined by spectroscopic methods. Electronic and geometric
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