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Functionalisation of saturated hydrocarbons. Part 9. Oxidation of patchouli alcohol by the ‘gif system’: Isolation and organoleptic properties of three new ketonic derivatives

✍ Scribed by Derek H. R. Barton; Jean-Claude Belœil; Annick Billion; Jean Boivion; Jean-Yves Lallemand; Simone Mergui


Publisher
John Wiley and Sons
Year
1987
Tongue
German
Weight
389 KB
Volume
70
Category
Article
ISSN
0018-019X

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✦ Synopsis


F 91 190 Gif-sur-Yvette Dedicated to Prof. Vlndo Prrlog on the occasion of his 80th birthday ( 17. X. 86) Oxidation of patchouli alcohol (1) using the 'Gif systcm' afforded as major isolated products three new ketonic derivatives 1618. The structures of' these compounds were established by spectral techniques including 2D-NMR. Ketones 16-18 display interesting organoleptic properties. ') Part 8: [I].