Functional group contributions to the auger spectra of methyl cyanide and methyl isocyanide
β Scribed by R.R. Rye; J.T. Yatess Jr.; M.R. Albert
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- English
- Weight
- 979 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0368-2048
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Ab initio (STO-3G) geometry-optimized calctdations have been performed on methyl and trifluoromethyl cyanide and isocyanide, and energies of isomerization of 24.1 and 11.5 kcal/mole, respectively have been calculated. Activation barriers of 87.8 and 80.0 kwl/mole are predicted for the isomerization
## Abstract Membranes based on dimethyl and methylβphenylsiloxane were synthesized and then fully characterized. Transport properties and mechanical behavior were determined as a function of different methyl/phenyl group ratios and the effects of these groups on results were established. Membrane t