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Functional Analysis of MycE and MycF, Two O-Methyltransferases Involved in the Biosynthesis of Mycinamicin Macrolide Antibiotics

✍ Scribed by Shengying Li; Yojiro Anzai; Kenji Kinoshita; Fumio Kato; David H. Sherman


Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
431 KB
Volume
10
Category
Article
ISSN
1439-4227

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✦ Synopsis


Abstract

Mg motors: We characterized the in vitro function of MycE and MycF, two O‐methyltransferases involved in the biosynthesis of mycinamicin antibiotics. Each enzyme was confirmed to be an S‐adenosyl‐L‐methionine (SAM)‐dependent deoxysugar methyltransferase. Their optimal activities require the presence of Mg^2+^. With the reconstituted in vitro assays, the order of mycinamicin VI→III→IV in the post‐PKS (polyketide synthase) tailoring pathway of mycinamicin was unambiguously determined.magnified image