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Fulvenes acting as 4π components in an intramolecular [4+2]cycloaddition reaction: Entry into the novel 6-oxatricyclo[6.4.0.02,10]dodeca-2,11-diene ring system

✍ Scribed by M. Shanmugasundaram; R. Raghunathan

Publisher: Elsevier Science
Year: 1999
Tongue: French
Weight: 104 KB
Volume: 40
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(99)00898-9

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✦ Synopsis

Intramolecular [4+2] eyeloaddition of fulvenes 2a,b gives 6-oxatricyclo[6.4.0.02"l°]dedeca -2,1 l-diene-[4,5-a]naphtho-endo 9-carboxylie acid alkyl esters 3a,b. Compounds 3a,b are the first representatives of this bridged la'icyelic ring system.

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