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Fullerene receptor based on calix[5]arene through metal-assisted self-assembly

✍ Scribed by Takeharu Haino; Hiromi Araki; Yuko Yamanaka; Yoshimasa Fukazawa

Publisher: Elsevier Science
Year: 2001
Tongue: French
Weight: 149 KB
Volume: 42
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)00420-8

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✦ Synopsis

A self-assembled fullerene receptor based on calix[5]arene has been developed. Silver cation complexation held together the two calix[5]arenes with bipyridine units providing a large enough cavity to take up C 60 or C 70 . The formation of the supramolecular complex with C 60 or C 70 was established by using the electrospray mass spectrometry.

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