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Fullerene-based macromolecules from photochemical reactions of [60]fullerene and triethylamine

✍ Scribed by Bin Ma; Glenn E. Lawson; Christopher E. Bunker; Alex Kitaygorodskiy; Ya-Ping Sun


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
426 KB
Volume
247
Category
Article
ISSN
0009-2614

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✦ Synopsis


60]fullerene-triethylamine macromolecules are obtained from photoinduced electron transfer-proton transfer reactions. The material is characterized by photon correlation spectroscopy of quasi-elastic light scattering, matrix-assisted laser desorption ionization time-of-flight mass spectrometry, NMR and FT-IR techniques. The electronic absorption and emission properties of the material are studied. Because the macromolecules likely contain intramolecular redox pairs, the possibility of intramolecular exciplexes is examined and discussed.


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