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Full differentiation and assignment of boron species in the electrolytes Li2B6O9F2 and Li2B3O4F3 by solid-state 11B NMR spectroscopy

✍ Scribed by Thomas Bräuniger; Thomas Pilz; C. Vinod Chandran; Martin Jansen


Book ID
116708750
Publisher
Elsevier Science
Year
2012
Tongue
English
Weight
368 KB
Volume
194
Category
Article
ISSN
0022-4596

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Two new solid solutions Li 2-x La (1+x)/3 ᮀ (2x-1)/3 B 2 O 6 F (B = Ta, Nb) have been synthesized in powder form by solid-state synthesis. Their composition domain corresponds to 0.6 Յ x Յ 1.1 for the Ta compounds and to 0.7 Յ x Յ 1.0 for the Nb compounds. The structural study has been performed by