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Full and Partial Deuterium Solvent Isotope Effect Studies of α-Thrombin-Catalyzed Reactions of Natural Substrates

✍ Scribed by Zhang, Daoning; Kovach, Ildiko M.

Book ID
127183157
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
101 KB
Volume
127
Category
Article
ISSN
0002-7863

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In a recent publication2 the mechanism of the reaction of i-arylethyltrimethylammonium ions with ethoxide ion in ethanol at 70° was shown to be E2. The transition state for this process involved extensive proton transfer to base as exhibited by the observed trend in hydrogendeuterium isotope effects