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FTIR study of the hydrogen bond symmetry in protonated homodimers of pyridine and collidine in solution

✍ Scribed by S.M. Melikova; K.S. Rutkowski; A.A. Gurinov; G.S. Denisov; M. Rospenk; I.G. Shenderovich


Book ID
116758415
Publisher
Elsevier Science
Year
2012
Tongue
English
Weight
387 KB
Volume
1018
Category
Article
ISSN
0022-2860

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The "N NMR chemical shifts of ten substituted pyridines (B) and their complexes with trifluoroacetic acid (AHB) were measured at the natural abundance level in dichloromethane. The plot of the relative chemical shifts [A6("N) = G(AHB) -6(B)] against ApK, gives a titration curve which reflects a prot