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FTIR Study of Hydrogen Bonding of Blends of Poly(mono n-alkyl itaconates) with Poly(N,N-dimethylacrylamide) and Poly(ethyloxazoline)

✍ Scribed by Meaurio, E.; Cesteros, L.C.; Katime, I.

Book ID
120548231
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
369 KB
Volume
30
Category
Article
ISSN
0024-9297

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FT-IR Study of Blends and Complexes of P
FT-IR Study of Blends and Complexes of Poly(mono n-alkyl itaconates) with Poly(N,N-dimethylacrylamide) and Poly(ethyloxazoline)
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## Abstract **Summary:** This paper reports an FT‐IR study of blends and complexes of poly(mono __n__‐alkyl itaconates) with poly(__N__,__N__‐dimethylacrylamide) (PDMA) and poly(ethyloxazoline) (PEOX). Strong hydrogen bonding has been found and both polybases have shown similar acceptor strengths.

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Hydrogels of mono-n-alkyl itaconate/N-acrylamide have been synthesised. The swelling process at three different pH values (acid, neutral and basic) has been studied. The experimental data indicate that our hydrogels follow second-order swelling kinetics. According to this, the kinetic constant, K, ,

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## Abstract The binary polymeric systems formed by some poly(mono‐n‐alkyl itaconates) and poly(2‐vinylpyridine) or poly(4‐vinylpyridine) are studied. Depending on the solvent, two different types of material have been synthesized. On the one hand, using methanol as common solvent, we have obtained