✦ LIBER ✦

FTIR studies of the kinetics and mechanism for the reaction of Cl atom with formylchloride

✍ Scribed by H. Niki; P. D. Maker; C. M. Savage; L. P. Breitenbach

Publisher: John Wiley and Sons
Year: 1980
Tongue: English
Weight: 257 KB
Volume: 12
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550121203

No coin nor oath required. For personal study only.

✦ Synopsis

The rate constant for the reaction C1+ CHClO -HC1+ CClO was determined from relative decay rates of CHClO and CH&1 in the photolysis of mixtures containing Clz (-1 torr), CH3Cl (-1 torr), and 0 2 ( 4 . 1 torr) in 700 torr Nz. In such mixtures CHClO was generated in situ as a principal product prior to complete consumpjion of 0 2 . The value of k(C1+ CHClO)/k(Cl + CH3C1) = 1.6 f 0.2(3a) combined with the literature value of k(C1f CH3C1) = 4.9 X cm3/molecule sec gives k(C1+ CHClO) = 7.8 X cm3/molecule sec at 298 f 2 K, in excellent agreement with a previous value of (7.9 f 1.5) X cm3/molecule sec determined by Sanhueza and Heicklen [J. Phys. Chem., 79,7 (1975)]. Thus this reaction is approximately 100 times slower than the corresponding reactions of aldehydes and alkanes with comparable C-H bond energies (595 kcal/mol).

📜 SIMILAR VOLUMES

Kinetics and mechanism of the reaction o

Kinetics and mechanism of the reaction of Cl atoms with HO2 radicals

✍ Véronique Riffault; Yuri Bedjanian; Georges Le Bras 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 363 KB 👁 2 views

The kinetics and mechanism of the reaction Cl ϩ HO 2 : products (1) have been studied in the temperature range 230-360 K and at total pressure of 1 Torr of helium using the discharge-flow mass spectrometric method. The following Arrhenius expression for the total rate constant was obtained either fr

Computational studies on the mechanism a

Computational studies on the mechanism and kinetics of Cl reaction with C2H5I

✍ Xiu-Juan Jia; You-Jun Liu; Jing-Yu Sun; Hao Sun; Fang Wang; Zhong-Min Su; Xiu-Me 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 337 KB 👁 2 views

The dual-level direct kinetics method has been used to investigate the multichannel reactions of C(2)H(5)I + Cl. Three hydrogen abstraction channels and one displacement process are found for the title reaction. The calculation indicates that the hydrogen abstraction from -CH(2)- group is the domina

Kinetic studies of Cl-atom reactions wit

Kinetic studies of Cl-atom reactions with selected aromatic compounds using the photochemical reactor-FTIR spectroscopy technique

✍ Jichun Shi; Mary Jo Bernhard 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 143 KB 👁 2 views

Relative rate constant measurements have been carried out on the Cl-atom reactions with benzene, chlorobenzene, toluene, xylene, and styrene in 740 torr of air at room temperature (295 K), using the photochemical reactor-FTIR spectroscopy technique. The Cl atoms were generated by the UV photolysis o

Theoretical studies on the mechanism and

Theoretical studies on the mechanism and kinetics of the reaction of F atom with NCO radical

✍ Zheng-Yu Zhou; Li Guo; Hong-Wei Gao 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 136 KB 👁 2 views

## Abstract The reaction of a F atom with an NCO radical was studied at 6‐311+g\* level, using DFT methods. All geometries, vibrational frequencies, and energies of different stationary points were calculated by HF, UMP2, and DFT methods, and the results agreed with the experimental values. The vib

FTIR study of the Cl- and Br-atom initia

FTIR study of the Cl- and Br-atom initiated oxidation of trichloroethylene

✍ V. Catoire; P. A. Ariya; H. Niki (Deceased); G. W. Harris 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 198 KB 👁 2 views

The Cl-and Br-initiated oxidations of CHCl"CCl 2 in 700 torr of air at 296 K have been studied using a Fourier transform infrared spectrometer. Rate constants k(Cl ϩ and were determined using a relative rate technique with ethane and ethylene as Ϫ 1 Ϫ 1 molecule s references, respectively. The majo

Kinetics of the reactions of pinonaldehy

Kinetics of the reactions of pinonaldehyde with OH radicals and with Cl atoms

✍ Barbara Nozière; Markus Spittler; Lars Ruppert; Ian Barnes; Karl H. Becker; Manu 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 193 KB 👁 2 views

The rate constant for the reaction of OH radicals with pinonaldehyde has been measured at 293 Ϯ 6 K using the relative rate method in the laboratory in Wuppertal (Germany) using photolytic sources for the production of OH radicals and in the EUPHORE smog chamber facility in Valencia (Spain) using th