FTIR-spectroscopy of molecular clusters in pulsed supersonic slit-jet expansions
✍ Scribed by Häber, Thomas; Schmitt, Ulrich; Suhm, Martin A.
- Book ID
- 120016920
- Publisher
- Royal Society of Chemistry
- Year
- 1999
- Tongue
- English
- Weight
- 223 KB
- Volume
- 1
- Category
- Article
- ISSN
- 1463-9076
- DOI
- 10.1039/A907264K
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The infrared spectrum of CHCIFz (freon 22, chlorodifluoromethane) in the range of the CH stretching fundamental v, and the two CF stretching fundamentals vj and vs has been measured in a supersonic free jet expansion with rotational temperatures of about 50 K and resolutions up to 0.004 cm-'. The fi
The rotational temperature behaviour in adiabatic jet expansion of molecular nitrogen is investigated over a wide range of stagnation density and nozzle diameter values using coherent anti-Stokes Raman spectroscopy (CARS). Estimates of rotational collisional numbers are made for both (N2 + N2) and (
Several rotational subbands of the bromomethylene (HCBr) and deuterated bromomethylene (DCBr) A ˜1AЉ 4 X ˜1AЈ origin band in the region of 830 -840 nm have been recorded under slit-jet cooled conditions that result in rotational and translational temperatures of approximately 20 K. The radical was f