FTIR and Reaction Kinetics Studies of the Hydrodehalogenation of CF 2 Br 2 , CH 2 Br 2 , and CD 2 Br 2 over a Pd/γ-Al 2 O 3 Catalyst
✍ Scribed by Borovkov, Victor Yu.; Kulkarni, Parag P.; Kovalchuk, Vladimir I.; d'Itri, Julie L.
- Book ID
- 126110603
- Publisher
- American Chemical Society
- Year
- 2004
- Tongue
- English
- Weight
- 106 KB
- Volume
- 108
- Category
- Article
- ISSN
- 0022-3654
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The kinetics of the title reactions have been studied using the discharge-flow mass spectrometic method at 296 K and 1 torr of helium. The rate constant obtained for the forward reaction (1), using three different experimental approaches (kinetics of Br Br ϩ IBr : I ϩ Br 2 consumption in excess of
## Abstract The rate coefficients for the reactions of Cl atoms with CH~3~Br, (__k__~1~) and CH~2~Br~2~, (__k__~2~) were measured as functions of temperature by generating Cl atoms via 308 nm laser photolysis of Cl~2~ and measuring their temporal profiles via resonance fluorescence detection. The m