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FT-IR study of the brønsted acidity of phosphated and sulphated silica catalysts

✍ Scribed by M. Lion; M. Maache; J.C. Lavalley; G. Ramis; G. Busca; P.F. Rossi; V. Lorenzelli


Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
329 KB
Volume
218
Category
Article
ISSN
0022-2860

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H 2'AI and %i solid-state NMR was used to determine the geometry of the Brsnsted acid site in zeolites. The mean distance between acidic protons in bridging hydroxyl groups and the nearest framework Al atom is 2.38 ? 0.04 8, in zeolite H-Y and 2.48 2 0.04 A in H-ZSM-5. The quadrupole frequency of fr