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FT-IR spectroscopic study on conformational equilibria of [Leu]5-enkephalin in DMSO and 2H2O solutions

✍ Scribed by Takahiro Takekiyo; Minoru Kato; Yoshihiro Taniguchi


Publisher
Elsevier Science
Year
2005
Tongue
English
Weight
260 KB
Volume
119
Category
Article
ISSN
0167-7322

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Polyethylene (PE) fdm is used as a matrix for studying temperature-dependent equilibria by IR spectroscopy; the film is impregnated with Cp%(CO)z (Cp%$-CsMes) using supercritical CO, and subsequently saturated with HORe (RF= (CFs)zCH or (CFs)sC). At 200 K, the equilibrium between Cp\*Ir(CO)z and the