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FT-EPR Study of Photoinduced Electron Transfer in a Micellar System

✍ Scribed by Levstein, P. R.; Willigen, H. Van; Ebersole, M.; Pijpers, F. W.


Book ID
120066781
Publisher
Taylor and Francis Group
Year
1991
Tongue
English
Weight
429 KB
Volume
194
Category
Article
ISSN
1542-1406

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The photoinduced electron transfer from zinc tetrakis(4-sulfonatophenyl)porphyrin (ZnTPPS) to duroquinone (DQ) in several micellar solutions was investigated with Fourier transform-electron paramagnetic resonance ( Ff-EPR). The measurements give information on the formation and decay of free radical

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The spin-correlated radical pairs (SCRPs) formed by photoinduced electron transfer from zinc tetrakis(4-sulfonatophenyl)porphyrin (ZnTPPS) to quinones in micelles of the cationic surfactant cetyltrimethylammonium chloride (CTAC) were studied by means of Fourier transform EPR (FT-EPR). It is shown th