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From Supramolecular Block Copolymers to Advanced Nano-Objects

✍ Scribed by Jean-François Gohy; Bas G. G. Lohmeijer; Ulrich S. Schubert

Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
248 KB
Volume
9
Category
Article
ISSN
0947-6539

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✦ Synopsis

Abstract

The formation of asymmetric bis‐complexes, based on terpyridine ligands and ruthenium ions, is described as a powerful tool for the self‐assembly of polymer blocks end‐functionalized with terpyridine units. This is illustrated in this contribution for the synthesis of amphiphilic metallo‐supramolecular block copolymers, which are further used to produce aqueous micelles. Finally, the reversibility of the supramolecular bond opens new avenues for the preparation and manipulation of these nano‐objects.

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