𝔖 Bobbio Scriptorium
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From simple electrolyte solutions through polymer electrolytes to superionic rubbers: some fundamental considerations

✍ Scribed by Angell, C. Austen; Imrie, Corrie T.; Ingram, Malcolm D.


Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
242 KB
Volume
47
Category
Article
ISSN
0959-8103

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✦ Synopsis


A general discussion is presented for the conductivityÈviscosity and viscosityÈtemperature relationships in polymer electrolytes in the context of systematizing the e †orts to obtain higher ionic conductivities at ambient temperatures. Topics discussed include : the Walden rule, glassÈrubber and rubberÈmelt transitions, the strengthÈfragility concept, the VogelÈFulcherÈ Tammann and WilliamsÈLandelÈFerry equations, the chelation e †ect and the decoupling of ionic transport from the structural relaxation processes. 1998 ( Society of Chemical Industry