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From Silylenes and Disilenes to a Tetrasilabuta-1,3-diene and Related Compounds

โœ Scribed by Manfred Weidenbruch

Publisher
John Wiley and Sons
Year
2005
Weight
15 KB
Volume
36
Category
Article
ISSN
0931-7597

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The reaction of hexakis(2,4,6-triisopropylphenyl)tetrasilabuta-1,3-diene R 2 Si=SiRยฑSiR=SiR 2 (1) with atmospheric oxygen furnishes the oxidation product R 2 Si(O) 2 SiROSiR(O) 2 SiR 2 (5) by oxygen insertion into all SiยฑSi bonds. However, treatment of 1 with meta-chloroperoxobenzoic acid provides R

Ammonia and Chlorine Additions to a Tetr
Ammonia and Chlorine Additions to a Tetrasilabuta-1,3-diene: Conglomerate versus Racemate Crystallization [1]
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Treatment of hexakis(2, 4, tetrasilabuta-1,3-diene (1), R 2 Si=SiRยฑSiR=SiR 2 , with ammonia and chlorine furnishes the correspondingly substituted 1,4diaminotetrasilane (3) and 1,2,3,4-tetrachlorotetrasilane (6). While product 6 crystallizes as a racemate, 3 forms a con-glomerate of enantiomerical