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From Serendipitous Assembly to Controlled Synthesis of 3d–4f Single-Molecule Magnets

✍ Scribed by Ledezma-Gairaud, M.; Grangel, L.; Aromí, G.; Fujisawa, T.; Yamaguchi, A.; Sumiyama, A.; Sañudo, E. C.

Book ID
124154311
Publisher
American Chemical Society
Year
2014
Tongue
English
Weight
635 KB
Volume
53
Category
Article
ISSN
0020-1669

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✍ Polyzou, Christina D. (author);Efthymiou, Constantinos G. (author);Escuer, Alber 📂 Article 📅 2013 🏛 International Union of Pure and Applied Chemistry 🌐 English ⚖ 519 KB

The importance of 3d/4f-metal cluster chemistry is outlined, and the employment of 2-pyridyl ketone- and 2-pyridyl oxime-based ligands for the preparation of low-nuclearity Ni^II^/Ln^III^ complexes (Ln = lanthanide) is reviewed. The synthetic utility of the “metal complexes as ligands” and “one-pot”