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From sequencamers to foldamers? Tetrameric furanose carbopeptoids from cis- and trans-5-aminomethyl-tetrahydrofuran-2-carboxylates

✍ Scribed by Daniel D. Long; Natasha L. Hungerford; Martin D. Smith; Dominic E.A. Brittain; Daniel G. Marquess; Timothy D.W. Claridge; George W.J. Fleet

Book ID: 104260908
Publisher: Elsevier Science
Year: 1999
Tongue: French
Weight: 238 KB
Volume: 40
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(99)00110-0

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✦ Synopsis

The synthesis of three stereoisomeric cis-and trans-5-azidomethyl-tetrahydrofuran-2carboxylates in which a ketal-protected cis-diol unit is present is described. The monomers undergo efficient oligomerisation to tetrameric carbopeptoids in which the diol protection facilitates ready purification by chromatography which augurs well for the formation of homogeneous higher polymers.

📜 SIMILAR VOLUMES

Tetrahydrofuran amino acids: Secondary s

Tetrahydrofuran amino acids: Secondary structure in tetrameric and octameric carbopeptoids derived from a D-allo 5-(aminomethyl)tetrahydrofuran-2-carboxylic acid

✍ Hungerford, Natasha L.; Claridge, Timothy D. W.; Watterson, Mark P.; Aplin, Robi 📂 Article 📅 2000 🏛 Royal Society of Chemistry ⚖ 322 KB

ChemInform Abstract: Tetrahydrofuran Ami

ChemInform Abstract: Tetrahydrofuran Amino Acids: Secondary Structure in Tetrameric and Octameric Carbopeptoids Derived from a D-allo 5-(Aminomethyl)tetrahydrofuran-2-carboxylic Acid.

✍ Natasha L. Hungerford; Timothy D. W. Claridge; Mark P. Watterson; Robin T. Aplin 📂 Article 📅 2001 🏛 John Wiley and Sons ⚖ 26 KB 👁 2 views

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