Rhodium and Iridium Pyrazolato Blues
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Cristina Tejel; Miguel A. Ciriano; JosΓ© A. LΓ³pez; Fernando J. Lahoz; Luis A. Oro
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Article
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1998
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John Wiley and Sons
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English
β 124 KB
The staggered arrangement of the two dimers in 1 facilitates the formation of an almost linear chain of four metal centers that is held together by a nonsupported metal-metal bond. The intense color of the compounds and the fractional oxidation states of the metal atoms can be explained by electron