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From p-benzoquinone to cyclohexane chirons: first asymmetric synthesis of (+)-rengyolone and (+)- and (−)-menisdaurilide

✍ Scribed by Felix Busqué; Mariona Cantó; Pedro de March; Marta Figueredo; Josep Font; Sonia Rodrı́guez

Book ID
104359884
Publisher
Elsevier Science
Year
2003
Tongue
English
Weight
367 KB
Volume
14
Category
Article
ISSN
0957-4166

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✦ Synopsis

Starting from a common, easily available, enantiopure monoketal of p-benzoquinone, the synthesis of a large number of cyclohexane chirons has been achieved. The first synthesis of (+)-rengyolone and (+)-and (-)-menisdaurilide has been performed from one of these new building blocks. The wide variety of functional groups of this series of chirons makes them useful for subsequent synthetic processes.

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