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From Concentration Profiles to Polymer Osmotic Equations of State

✍ Scribed by Chris I. Addison; Jean-Pierre Hansen; Ard A. Louis

Book ID
102116201
Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
131 KB
Volume
6
Category
Article
ISSN
1439-4235

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✦ Synopsis

Figure 6. a) Three different concentration profiles from simulations with different numbers of polymers and gravitational strengths, but with the product n s l cm a 2 held constant. Note that b) the equations of state generated from the concentration profiles are practically identical, as are c) the concentration profiles when scaled by the gravitational length.

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Recently, the chain-of-rotators equation of state derived from the rotational partition function was extended to polymers. Values of the three equation of state (EOS) parameters were obtained from fitting with experimental pressure-volumetemperature data and the parameters were correlated with the s