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Friedel-Crafts reactions of some conjugated epoxides

โœ Scribed by Taylor, Stephen K.; Clark, Daniel L.; Heinz, Karl J.; Schramm, Scott B.; Westermann, Cindy D.; Barnell, Koleen K.

Book ID
126975338
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
679 KB
Volume
48
Category
Article
ISSN
0022-3263

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The novel secondary Friedel-Crafts acylation products of the arenes, dimethyl resorcinol, m-xylene, m-methylanisole and m-chlorotoluene using dichloroacetylchloride and anhydrous AlCIs are described. The formation of the unexpected products has been shown to depend on the nucleophilicity of the aren